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A color and fluorescence turn-on H2S probe is synthesized, achieving real-time detection of H2S in pure water solution with high selectivity. Importantly, the probe is able to sense H2S gas in air via the probe-deposited test paper, which has been successfully used for food spoilage identification.The present study reports an aqueous synthesis approach towards Cu-In-Se/ZnS quantum dots with emission in the near-infrared spectral range. The photoluminescence of the dots can be effectively controlled by adjusting the sulfur source, to achieve increased quantum yields (four times higher) and red-shifted emission peaks (from 809 nm to 830 nm).Herein, a novel co-catalytic ferrocene/hemin/G-quadruplexes/Fe3O4 nanoparticles (Fc/HGQs/Fe3O4) nanocomposite was synthesized to significantly magnify the electrochemical signal of ferrocene (Fc) using the synergistic catalysis of hemin/G-quadruplexes (HGQs) and Fe3O4 nanoparticles as hydrogen peroxide enzyme mimics for the construction of ultrasensitive electrochemical biosensors. The fabricated electrochemical biosensor can achieve ultrasensitive detection of miRNA-155 ranging from 0.1 fM to 1 nM, as well as a limit of detection of 74.8 aM. This strategy provides a new route to exploring efficient signal labels for signal amplification and provides an impetus to find novel methods for the construction of biosensors for biological detection and the early clinic diagnosis of diseases.Oligophenyleneethynylenes (OPEs) are prominent building blocks with exciting optical and supramolecular properties. However, their generally small spectroscopic changes upon aggregation make the analysis of their self-assembly challenging, especially in the absence of additional hydrogen bonds. Herein, by investigating a series of OPEs of increasing size, we have unravelled the role of the conjugation length on the self-assembly properties of OPEs.Lithium is the lightest metal element. To date, little is known about its quantized nuclear motion in nanoscale porous structures. Endohedral fullerene Li+@C60 is an ideal porous system for studying such a quantized motion. Recent studies suggest that the anions surrounding the C60 cage exterior and a slight cage distortion can alter the potential field in the cage interior and thus the nuclear wave function of Li+. It has yet to be clarified how the electronic state, particularly the flexible π electron cloud of the C60 cage, is associated with (de)localization of the Li+ wave function. Focusing on the [Li+@C60]PF6- crystal, we constructed a local structure model considering the PF6- coordination and the cage distortion. We developed model functions that fit the post-Hartree-Fock potential energy surface for the Li+ motion and its decomposed components, four interaction energy surfaces. The decomposition clarified the origins of the shell-like adsorbent potential and the potential wells therein. The Fourier grid Hamiltonian method allowed us to obtain low-energy Li+ wave functions. The ground state is nearly two-fold degenerate, and its wave functions are mostly localized underneath two C6 rings, near the disordered sites of Li+ in the X-ray crystal structure. By extending the energy decomposition analysis within the clamped-nuclei approximation to incorporate the delocalization of nuclear wave functions, we demonstrated that the ground state is stabilized by the polarization, dispersion, and electrostatic interactions. Beyond the common picture of Li+ moving in a classical electrostatic field, our approach will deepen the understanding of the flexible Li+ wave function confined in a polarizable porous structure by various intermolecular interactions.Amino acids and peptides are essential components in the biochemical industry. [https://www.selleckchem.com/products/PI-103.html PI-103] The final products are employed in a wide range of applications and are often synthesized by fermentation and purified in a complex downstream process. One possible separation step is using an additional solvent to lower the solubility of the desired product and, thus, promote the crystallization of the particular component. Therefore, it is crucial to have accurate knowledge of the solubility of these components. In this work, the solubilities of 20 proteinogenic amino acids and 21 peptides in aqueous 2-propanol solutions were gravimetrically determined. Additionally, the pH values of the saturated liquid phases were measured and the crystal structures of solid crystals were analysed using X-ray diffraction. The anti-solvent 2-propanol caused a decrease in the solubilities of the amino acids and peptides upon increasing its mass fraction. Exceptions were found for amino acids with aromatic substituents, l-phenylalanine and l-tyrosine. The solubility of 15 amino acids and 18 peptides was successfully modelled using the equation of state PC-SAFT that used recently determined melting properties of the amino acids and peptides as input data.Monolayer Cu2Se is a novel two-dimensional (2D) material, but its fundamental properties have not been adequately investigated. Hence, in this work, we investigate the adsorption behaviors of various elements on monolayer Cu2Se using first-principles density functional theory calculations. The considered elements include metals (Li, Na, Al, K, Ca, Fe, Co, Ni, Cu, Zn, Pd, Ag, Pt, and Au) and nonmetals (H, B, C, N, and O). The adsorption of all these atoms is exothermic with substantial binding energy. Although monolayer Cu2Se forms strong bonds with all the adsorbates, it still preserves its layered structure. This atomic adsorption substantially modifies the electronic properties of the 2D Cu2Se. In particular, N, Fe, Co, Ni, and Au adatoms give rise to mid-gap states within the bandgap of monolayer Cu2Se; furthermore, except for Au, the other adatoms exhibit magnetic moments. Naturally, this electronic structure modification also leads to changes in the work function of monolayer Cu2Se. The present work demonstrates that atomic adsorption can optimize the properties of monolayer Cu2Se.We report a mitochondria-targeted near-infrared probe (NRh-O) for frequency upconversion luminescence (FUCL) imaging of hypoxia. Under hypoxic conditions, NRh-O rapidly responds to release the FUCL product NRh (λex/em = 850/825 nm) with high sensitivity and selectivity in mitochondria. This highlights the potential application of a hypoxia-responsive probe in early clinical diagnosis.