An extra S4 activity starts hyperpolarizationactivated HCN programs

We establish the quantum fluctuations ΔQ_B^2 of the charge Q_B accumulated at the boundary of an insulator as an integral tool to characterize phase transitions where a direct gap closes (and reopens), typically occurring for insulators with topological properties. The power of this characterization lies in its capability to treat different kinds of insulators on equal footing, being applicable to transitions between topological and nontopological band, Anderson, and Mott insulators alike. In the vicinity of the phase transition, we find a universal scaling ΔQ_B^2(E_g) as a function of the gap size E_g and determine its generic form in various dimensions. For prototypical phase transitions with a massive Dirac-like bulk spectrum, we demonstrate a scaling with the inverse gap in one dimension and a logarithmic one in two dimensions.Solid-state quantum dots are promising candidates for efficient light-matter interfaces connecting internal spin degrees of freedom to the states of emitted photons. However, selection rules prevent the combination of efficient spin control and optical cyclicity in this platform. By utilizing a photonic crystal waveguide we here experimentally demonstrate optical cyclicity up to ≈15 through photonic state engineering while achieving high fidelity spin initialization and coherent optical spin control. These capabilities pave the way towards scalable multiphoton entanglement generation and on-chip spin-photon gates.We present the formation of homonuclear Cs_2, K_2, and heteronuclear CsK long-range Rydberg molecules in a dual-species magneto-optical trap for ^39K and ^133Cs by one-photon UV photoassociation. The different ground-state-density dependence of homo- and heteronuclear photoassociation rates and the detection of stable molecular ions resulting from autoionization provide an unambiguous assignment. We perform bound-bound millimeter-wave spectroscopy of long-range Rydberg molecules to access molecular states not accessible by one-photon photoassociation. Calculations based on the most recent theoretical model and atomic parameters do not reproduce the full set of data from homo- and heteronuclear long-range Rydberg molecules consistently. This shows that photoassociation and millimeter-wave spectroscopy of heteronuclear long-range Rydberg molecules provide a benchmark for the development of theoretical models.Mixtures of ammonia and water are major components of the "hot ice" mantle regions of icy planets. The ammonia-rich ammonia hemihydrate (AHH) plays a pivotal role as it precipitates from water-rich mixtures under pressure. It has been predicted to form ionic high-pressure structures, with fully disintegrated water molecules. Utilizing Raman spectroscopy measurements up to 123 GPa and first-principles calculations, we report the spontaneous ionization of AHH under compression. Spectroscopic measurements reveal that molecular AHH begins to transform into an ionic state at 26 GPa and then above ∼69  GPa transforms into the fully ionic P3[over ¯]m1 phase, AHH-III, characterized as ammonium oxide (NH_4^+)_2O^2-.Because of their long coherence times and potential for scalability, semiconductor quantum-dot spin qubits hold great promise for quantum information processing. However, maintaining high connectivity between quantum-dot spin qubits, which favor linear arrays with nearest neighbor coupling, presents a challenge for large-scale quantum computing. In this work, we present evidence for long-distance spin-chain-mediated superexchange coupling between electron spin qubits in semiconductor quantum dots. We weakly couple two electron spins to the ends of a two-site spin chain. Depending on the spin state of the chain, we observe oscillations between the distant end spins. We resolve the dynamics of both the end spins and the chain itself, and our measurements agree with simulations. https://www.selleckchem.com/products/ZM-447439.html Superexchange is a promising technique to create long-distance coupling between quantum-dot spin qubits.We present results from the SPring-8 Angstrom Compact free electron LAser facility, where we used a high intensity (∼10^20  W/cm^2) x-ray pump x-ray probe scheme to observe changes in the ionic structure of silicon induced by x-ray heating of the electrons. By avoiding Laue spots in the scattering signal from a single crystalline sample, we observe a rapid rise in diffuse scattering and a transition to a disordered, liquidlike state with a structure significantly different from liquid silicon. The disordering occurs within 100 fs of irradiation, a timescale that agrees well with first principles simulations, and is faster than that predicted by purely inertial behavior, suggesting that both the phase change and disordered state reached are dominated by Coulomb forces. This method is capable of observing liquid scattering without masking signal from the ambient solid, allowing the liquid structure to be measured throughout and beyond the phase change.Quantum criticality, as a fascinating quantum phenomenon, may provide significant advantages for quantum sensing. Here we propose a dynamic framework for quantum sensing with a family of Hamiltonians that undergo quantum phase transitions (QPTs). By giving the formalism of the quantum Fisher information (QFI) for quantum sensing based on critical quantum dynamics, we demonstrate its divergent feature when approaching the critical point. We illustrate the basic principle and the details of experimental implementation using quantum Rabi model. The framework is applicable to a variety of examples and does not rely on the stringent requirement for particular state preparation or adiabatic evolution. It is expected to provide a route towards the implementation of criticality-enhanced quantum sensing.The intrinsic Hall effect allows for the generation of a nondissipative charge neutral current, such as a pure spin current generated via the spin Hall effect. Breaking of the spatial inversion or time reversal symmetries, or the spin-orbit interaction is generally considered necessary for the generation of such a charge neutral current. Here, we challenge this general concept and present generation and detection of a charge neutral current in a centrosymmetric material with little spin-orbit interaction. We employ bilayer graphene, and find enhanced nonlocal transport in the quantum Hall antiferromagnetic state, where spontaneous symmetry breaking occurs due to the electronic correlation.